本研究利用二氧化矽(SiO2)摻混1,3：2,4-二苯亞甲基山梨醇/聚乙二醇(DBS/PEG)有機膠所形成的複合材料，一方面改變SiO2的含量討論其有機膠的結構型態、流變性質、熱性質與分子間作用力;應用方面則加入電解質形成膠態電解質後觀察不同SiO2含量對導電度的影響。
在流變分析結果可知隨著SiO2的增加，都顯示有機膠的彈性模數G’ 可以有效的提升，且在較高形變量下較不易降低。由POM觀察到由DBS形成的馬爾他十字似球晶結構把SiO2排在球晶外，且TEM、SEM也觀察到SiO2聚集排列在DBS纖維的外面。由熱性質分析可由SiO2所形成一類似保護圈可提高有機膠的熱穩定性。由IR跟UV可觀察到SiO2的加入明顯影響DBS纖維自組裝行為然而不影響其苯環T-shap的穩定排列。導電度分析中導電度隨SiO2增加而提升。

In this study, we use the silicon dioxide (SiO2) blended composites 1,3:2,4- diphenylmethylene sorbitol / polyethylene glycol (DBS / PEG) formed by an organic gel, on the one hand to change the content of SiO2 discuss its organic gel structure , between the rheological properties, thermal properties and molecular forces; applications are added to the electrolyte be formed to colloidal electrolytes and observe the effects of different content on the SiO2.
By rheological analysis, with the increase of SiO2 shown organic rubber elastic modulus G 'can be effectively improved, and more difficult to reduce at higher deformation. By POM analysis ,a maltese cross spherulite-like structure and SiO2 will come in the spherulite-like structure outside, and TEM, SEM was also observed by the SiO2 gather outside on the DBS fibers.By the thermal stability analysis , added to SiO2 can increase the thermal properties.By IR and UV analysis , added SiO2 to significantly affect DBS fiber self-assembly . However, the DBS phenyl rings stack as T-shap stability does not affect.By Conductivity analysis ,Conductivity increases with SiO2 content.

目錄
致謝........................................................I
中文摘要...................................................II
英文摘要..................................................III
目錄.......................................................IV
圖目錄....................................................VII
表目錄....................................................XII
第一章 緒論.................................................1
	1-1 前言............................................1
	1-2 研究目的........................................2
第二章 理論基礎.............................................3
	2-1 流變學概念......................................3
	   2-1-1 黏彈模型...................................4
	   2-1-2 剪切黏度...................................6
	   2-1-3 動態流變性質...............................7
	2-2 有機膠..........................................8
	2-3 小角度X光散射儀
            (Small angle X-ray scattering;SAXS)............10
	2-4 交流阻抗分析儀 (AC Impedance)..................12
第三章 文獻回顧............................................14
	3-1 小分子有機膠...................................14
	   3-1-2 成膠劑對掌性..............................17
	3-2 DBS膠化劑......................................19
	   3-2-2  DBS有機膠................................22
	3-3 膠態電解質.....................................28
第四章 實驗................................................33
	4-1 實驗藥品.......................................33
	4-2 實驗設備.......................................34
	4-3 實驗流程.......................................38
	   4-3-1 配置不同含量SiO2 的DBS/PEG有機膠..........38
	   4-3-2 配置不同含量SiO2 的DBS/PEG電解質..........41
	4-4 實驗樣品製備...................................43
	   4-4-1 流變儀(Rheometer).........................43
	   4-4-2 偏光顯微鏡POM.............................44
	   4-4-3 傅式紅外線光譜儀FTIR......................44
	   4-4-4 紫外線/可見光光譜UV/Vis...................44
	   4-4-5 掃描式電子顯微鏡SEM.......................45
	   4-4-6 穿透式電子顯微鏡TEM.......................45
	   4-4-7 小角度X光散射儀SAXS.......................45
	   4-4-8 交流阻抗分析儀 EIS........................46
第五章 結果與討論..........................................47
	5-1 不同含量SiO2對DBS/PEG有機膠的分子作用力
            分析...........................................47
           5-1-1 分子間氫鍵作用力..........................47
	   5-1-2 苯環交互作用力............................52
	5-2 不同含量SiO2對DBS/PEG有機膠的結構與型態 
            學影響.........................................55
	5-3 不同含量SiO2對DBS/PEG有機膠流變性質影
            響.............................................68
	   5-3-1 振幅掃描(amplitude sweep).................68
	   5-3-2 頻率掃描(frequency sweep).................70
	   5-3-3 有機膠熔解溫度 
                 Td(gel dissolution temperature)...........72
	   5-3-4 不同含量SiO2對DBS/PEG有機膠成膠時  
                 間(gel formation time)的影響..............74
        5-5 不同含量SiO2對DBS/PEG有機膠TGA熱重分 
            析.............................................80
        5-6 導電度(conductivity)...........................83
第六章 結論................................................88
第七章 參考文獻............................................90

圖目錄
圖2-1 彈性模式..............................................4
圖2-2 黏性模式..............................................4
圖2-3 Maxwell模式...........................................5
圖2-4 Voigt-Kelvin模式......................................5
圖2-5 膠體樹狀分類圖........................................9
圖2-6 物質結構探測示意圖...................................10
圖2-7 交流阻抗圖譜(Nyquist diagram)........................13
圖3-1 (a)固態纖維.
      (b)流體纖維..........................................14
圖3-2 (a)純DBS球晶
      (b)5%DBS-PEG 400球晶.................................15
圖3-3 (A)(B)雙螺旋纖維SEM圖
      (C)(D)雙螺旋纖維TEM圖
      (E)雙螺旋纖維示意....................................17
圖3-4 DBS結構式............................................19
圖3-5 分子內氫鍵圖.........................................20
圖3-6 分子間氫鍵圖.........................................20
圖3-7 DBS碳位標示圖........................................21
圖3-8 DBS在不同末端基PEG中成膠時間與溫度...................23
圖3-9 不同濃度2wt%(▲) ,3wt%(△),5wt%(○)DBS/PEG 
      Td流變圖.............................................23
圖3-10 相同濃度DBS與不同末端基 3%DBS/PEG (△),PEGme,
       (□) PEGdme(●)Td流變圖.............................24
圖3-11 純DBS場發掃描式電子顯微鏡...........................25
圖3-12 2wt% DBS/PPG(a)25℃(b)83℃(c)105℃(d)130℃..........25
圖3-13 DBS與St、MMA有機膠 TEM圖............................26
圖3-14 DBS堆疊式意圖.......................................27
圖3-15 DMDBS堆疊式意圖.....................................27
圖3-16 膠態電解液成膠示意圖................................28
圖3-17 不同末端基的寡聚物結構圖............................30
圖3-18 FS和MDBS加入Li/ PC電解質溶液之凝膠圖................32
圖4-1 不同含量SiO2 的DBS/PEG有機膠.........................38
圖4-2 EIS 樣品圖...........................................38
圖4-3 不同含量SiO2 的DBS/PEG有機膠.........................39
圖4-4 配置不同含量SiO2 的DBS/PEG有機膠實驗流程圖...........40
圖4-5 EIS樣品圖............................................41
圖4-6 配置不同含量SiO2 的DBS/PEG電解質實驗流程圖...........42
圖5-1 FT-IR  neat DBS、pure PEG400、pure SiO2 光譜.........49
圖5-2 FT-IR (a)不同含量SiO2 DBS/PEG 有機膠光譜.............49
圖5-2 FT-IR (b)不同含量SiO2 DBS/PEG 有機膠光譜.............50
圖5-3 苯環錯位示意圖.......................................52
圖5-4 苯環平行位移圖.......................................53
圖5-5 UV/vis 不同含量SiO2 DBS/PEG有機膠圖..................54
圖5-6 POM不同含量SiO2 DBS/PEG有機膠圖......................59
      (a) 0wt%SiO2
      (b) 3wt%SiO2 
      (c) 5wt%SiO2 
      (d) 7wt%SiO2
圖5-7 POM不同含量SiO2 DBS/PEG外圈有機膠圖..................59
      (a) 0wt%SiO2 
      (b) 3wt%SiO2 
      (c) 5wt%SiO2
      (d) 7wt%SiO2
圖5-8 POM升溫熔解0wt% SiO2 DBS/PEG有機膠圖.................60
      (a) 20oC 
      (b) 81.3oC
      (c) 90.4oC
圖5-9 POM升溫熔解3wt% SiO2 DBS/PEG有機膠圖.................60
      (a) 20oC 
      (b) 88.4oC 
      (c) 95.6oC
圖5-10 POM升溫熔解5wt% SiO2 DBS/PEG有機膠圖................61
      (a) 20oC 
      (b) 90.6oC 
      (c) 98.4oC	
圖5-11 POM升溫熔解7wt% SiO2 DBS/PEG有機膠圖................61
      (a) 20oC 
      (b) 94.8oC 
      (c) 103.1oC
圖5-12 SEM 0wt%SiO2 DBS/PEG...............................62 
      (a)未水洗
      (b)以去離子水洗
圖5-13 SEM 純SiO2粒子......................................62
圖5-14 SEM 不同含量SiO2 DBS/PEG 有機膠圖...................63
      (a)、(b) 3wt%SiO2 ，(c)、(d) 5wt%SiO2，(e)、(f)    
      7wt%SiO2
圖5-15 TEM 0wt%SiO2 DBS/PEG................................64
圖5-16 TEM 純SiO2粒子......................................64
圖5-17 TEM 不同含量SiO2 DBS/PEG 有機膠圖...................65
      (a)、(b) 3wt%SiO2 ，(c)、(d) 5wt%SiO2，(e)、(f) 
      7wt%SiO2
圖5-18 SAXS 0wt%SiO2 DBS/PEG...............................66
圖5-19 SAXS pure SiO2......................................66
圖5-20 SAXS 不同含量SiO2 DBS/PEG...........................67
圖5-21 3wt%DBS/PEG (0wt%SiO2) 振幅掃描圖...................69
圖5-22 不同含量SiO2 DBS/PEG 振幅掃描圖.....................69
圖5-23 3wt%DBS/PEG (0wt%SiO2)頻率掃描圖....................71
圖5-24 不同含量SiO2 DBS/PEG 頻率掃描圖.....................71
圖5-25 不同含量SiO2 DBS/PEG有機膠熔解溫度Td圖..............73
圖5-26 不同含量SiO2 DBS/PEG 160℃ 0min.....................75
圖5-27 不同含量SiO2 DBS/PEG 30℃ 30min.....................75
圖5-28 不同含量SiO2 DBS/PEG 30℃ 60min.....................75
圖5-29 不同含量SiO2 DBS/PEG 30℃ 90min.....................76
圖5-30 不同含量SiO2 DBS/PEG 30℃ 120min....................76
圖5-31 不同含量SiO2 DBS/PEG 30℃ 150min....................76
圖5-32 不同含量SiO2 DBS/PEG 30℃ 180min....................77
圖5-33 不同含量SiO2 DBS/PEG 30℃ 210min....................77
圖5-34 不同含量SiO2 DBS/PEG 30℃ 240min....................77
圖5-35 不同含量SiO2 DBS/PEG 30℃ 270min....................78
圖5-36 不同含量SiO2 DBS/PEG 30℃ 300min....................78
圖5-37 平均成膠時間 不同含量SiO2 DBS/PEG圖.................79
圖5-38 TGA 3wt% SiO2 DBS/PEG圖.............................81
圖5-39 TGA 5wt% SiO2 DBS/PEG圖.............................81
圖5-40 TGA 7wt% SiO2 DBS/PEG圖.............................82
圖5-41 不同含量SiO2 DBS/PEG最大熱裂解溫度圖................82
圖5-42 不同LiClO4比例PEG電解質導電度圖.....................85
圖5-43 不同含量 SiO2/PEG電解質導電度圖.....................86
圖5-44 不同含量 SiO2 DBS/PEG電解質導電度圖.................87

表目錄
表4-1 SiO2 DBS/PEG有機膠樣品含量表.........................39
表4-2 SiO2 DBS/PEG電解質樣品含量表.........................41
表5-1 DBS和PEG特性吸收峰...................................50
表5-2 矽氧特性吸收峰.......................................51
表5-3 SEM不同含量SiO2 DBS/PEG纖維直徑範圍與平均直徑表......63
表5-4 TEM不同含量SiO2 DBS/PEG纖維直徑範圍與平均直徑表......65
表5-5 SAXS SiO2 DBS/PEG d值比較表..........................67
表5-6 不同含量SiO2 DBS/PEG有機膠熔解溫度Td表...............73
表5-7 不同含量SiO2 DBS/PEG平均成膠時間表...................79
表5-8 不同LiClO4比例PEG電解質導電度表......................85
表5-9 不同含量 SiO2/PEG電解質導電度表......................86
表5-10 不同含量 SiO2 DBS/PEG電解質導電度表.................87

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