本研究以氯化銀/銀原子簇晶種合成法製備奈米銀線棒，將所製作的奈米銀棒製成奈米銀棒乙醇溶液之導電墨水。將感光性樹脂混合奈米銀棒浸塗於蜘蛛絲，會在蜘蛛絲親油端處形成紡錘體透鏡，藉由RGB雷射照射藉以觀察紡錘體透鏡之光子奈米噴流特徵，以期克服光學顯微鏡無法避免的繞射極限問題。藉由氯化銀薄膜複合加奈米銀棒提出一種嶄新的Orange II偶氮染料降解方法。我們將製備的奈米銀晶種在160℃環境下加入聚乙烯吡咯烷酮（PVP）及硝酸銀合成高展弦比的奈米銀線溶液，在室溫下利用往復式活塞唧筒衝擊奈米銀線溶液後得到低展弦比奈米銀棒，破壞與重新成長過程中節錄一系列TEM圖藉以說明奈米旗幟與奈米銀棒的成長機制，並與滲透理論相互印證。感光樹脂混合奈米銀棒的紡錘體在紅光(波長617nm)於3μm穿透厚度下產生的光子奈米噴流特徵接近繞射極限。氯化銀複合奈米銀棒薄膜在紫外和可見光照射下對Orange II偶氮染料的光催化降解具有完全脫色效果。

In this study, nano silver rods were prepared by silver chloride/silver cluster seed crystal synthesis method and UV exposure and the prepared silver nanorods glycol solution was applied to the conductive ink and photo curable resin coating. The photocurable resin mixed nano silver rod is dip coated on the spider silk, and a spindle lens is formed at the oleophilic end of the spider silk, and the photonic nano jet characteristics of the spindle lens are observed by RGB laser irradiation, in order to overcome the problem of diffraction limit that the optical microscope is hard to avoid.
This study proposes a process for fabricating nano-silver crystal seeds and silver nanowires / nanorods that were prepared by seed synthesis method The formed spider silk spindle is used to observe and study the photonic nanojet characteristics in order to overcome the problem of diffraction limit that the optical microscope is hard to avoid. It also proposes a renewal Orange II degradation method by a film of silver chloride and silver nanorods glycol solution. In this process, UV-irradiated silver chloride nanoparticles are added to ethylene glycol solution containing polyvinyl pyrrolidone (PVP) and silver nitrate at 160 C. With the seed crystal synthesis method, this process yielded a solution containing silver nanowires with high aspect ratio (AR) in the ambient, and using a reciprocating piston cylinder to impact the silver nanowires solution at room temperature to obtain a low aspect ratio silver nanorods, In the process of destruction and re-growth, a series of TEM images are recorded to illustrate the growth mechanism of the nano-flag and the nano-silver rod, and demonstrate the theory of percolation. The photonic nanojet characteristics of the spider silk spindle coating with photosensitive resin and nanorods mixed solution at red light (wavelength 617 nm) on a penetration thickness of 3 μm approach the diffraction limit. The silver chloride and nano-bar silver film has complete decolorization effect on the photocatalytic degradation of Orange II azo dye under ultraviolet and visible light irradiation.

目錄
第1章 導論
1.1前言	1
1.2文獻回顧	5 
1.2.1奈米銀線性質	5
1.2.1.1奈米銀線的製備方法	5
1.2.2奈米銀線棒與導電墨水	22
1.2.2.1滲透理論	35 
1.2.3感光性樹脂複合奈米銀棒紡錘體透鏡的光子奈米噴流	35
1.2.4 氯化銀薄膜複合奈米銀棒之偶氮染料降解	42
1.3研究動機	46 
第2章 實驗設計	48 
2.1奈米銀線製作	48 
2.1.1氯化銀晶種製備	48
2.1.2奈米銀線的製作與純化	55 
2.2 奈米銀棒與導電墨水的製作及奈米銀線溶液臨界濃度測定與片阻值關係	60
2.2.1奈米銀棒與導電墨水的製作	60 
2.2.2奈米銀線溶液臨界濃度測定與片阻值關係	65
2.3 感光性樹脂複合奈米銀棒蜘蛛絲紡錘體透鏡的光子奈米噴流	70 
2.3.1感光性樹脂複合奈米銀棒蜘蛛絲紡錘體透鏡的製作	70 
2.4 氯化銀薄膜複合奈米銀棒之偶氮染料降解	81 
2.4.1氯化銀薄膜複合奈米銀棒的製作	81 
第3章 結果與討論	85 
3.1奈米銀線合成	85 
3.2奈米銀棒與導電墨水的製作	86 
3.3感光性樹脂複合奈米銀棒紡錘體透鏡的光子奈米噴流	95 
3.4氯化銀複合奈米棒之偶氮染料降解	100 
第4章 結論	102 
第5章 參考文獻	103

圖目錄
圖 1-1(a)AAO模板AFM圖；(b)AAO模板截面的FE-SEM圖[11]	8
圖 1-2 AAO模板移除後的奈米銀線陣列SEM圖(a)上視圖；(b)上視放大圖；(c)橫截面；(d)較短的奈米銀線圖[11]	8
圖 1-3 晶種合成法步驟示意圖：利用銀晶種合成奈米銀線	14
圖 1-4 通過加入不同濃度的硝酸銀生長出不同展弦比的銀[21]	18
圖 1-5 孿生五面體銀晶種成長為奈米銀線[21]	18
圖 1-6 聚醚合成法製備奈米銀線，加入銅鹽之反應[20]	19
圖 1-7 來自DMF中奈米銀棒的奈米銀片的成長機制[41]	21
圖 1-8(a)乾燥後均勻的銀產生；(b)銀晶體的是寸大小之SEM照片[42]	25
圖 1-9 相對時間給予墨水的溫度分佈導致的質量損失百分比[42]	26
圖 1-10 備樣的圖案與尺寸[43]	30
圖 1-11 導電墨水A、B在不同基材上的片電阻[43]	31
圖 1-12 三種加熱的方法用不同時間乾燥後的片電組推移圖[44]	34
圖1-13不同光觸媒(N-doped TiO2 、AgCl、AgCl/Ag-bulk、AgCl/Ag-NP50 及AgCl/Ag-NP20)在可見光照射下對甲基藍染料降解效率比較[55]	44
圖 1-14 Orange II 偶氮染料之化學結構[62]	46
圖 2-1奈米銀線利用衝槌機構經管壁渦流式衝擊的機構圖	64
圖 2-2形成紡錘體的過程的示意圖	74
圖 2-3光子奈米噴流特性量測系統圖	79
圖 2-4正規化0.01 mm 標準試片	80
圖 2-5正規化0.01 mm 標準試片電腦數據分析圖	80
圖 2-6(a)對偶氮染料降解應用之示意圖(一)	83
圖 2-6(b)對偶氮染料降解應用之示意圖(二)	83
圖 2-6(c)對偶氮染料降解應用之示意圖(三)	84
圖 3-1 X射線衍射分析奈米氯化銀顆粒表面銀簇相對應的衍射峰	86
圖 3-2衝槌機構衝擊1000次加工未成長前奈米銀棒的TEM圖	87
圖 3-3衝槌機構衝擊1000次加工成長後奈米銀棒的TEM圖	88
圖 3-4漩渦式的機械交互作用加工後未成長前奈米銀棒的TEM圖	89
圖 3-5粉碎後未成長前奈米爆米花或鏤空銀棒的TEM圖	89
圖 3-6粉碎成長後的奈米銀棒滲透發端的TEM圖	90
圖 3-7粉碎後奈米銀簇聚在長出旗幟的奈米銀棒滲透開放端的TEM圖	90
圖 3-8孤島型奈米銀旗幟的TEM圖	92
圖 3-9紡錘體透鏡的光子奈米噴流	97
圖 3-10(a) 紡錘體透鏡的光子奈米噴流半高全寬	97
圖 3-10(b) 紡錘體透鏡的光子奈米噴流能量強度	98
圖 3-10(c) 紡錘體透鏡的光子奈米噴流衰減長度	98
圖 3-10(d) 紡錘體透鏡的光子奈米噴流焦距	99
圖 3-11蜘蛛絲的多孔隙結構具有超親水特性[22]	99
圖 3-12不同幾何形狀之奈米金屬結構其侷域性表面電漿共振之電場強度分佈圖[63~65]	100
圖 3-13氯化銀複合奈米銀棒對Orange II偶氮有機染料降解速率	101

表目錄
表 1-1奈米銀線結構形狀最常用的分類	5
表 1-2奈米銀線最常用的合成法[10~21]	6
表 1-3 AAO模板法合成法實驗步驟及參數或內容[11]	6
表 1-4晶種合成法之一的實驗步驟及參數或內容[13]	9
表 1-5晶種合成法之二的實驗步驟及參數或內容[14]	11
表 1-6聚醚合成法之一的實驗步驟及參數或內容[18]	14
表 1-7聚醚合成法之二的實驗步驟及參數或內容[19]	15
表 1-8聚醚合成法之三的實驗步驟及參數或內容[20]	16
表 1-9三種典型製備複雜的奈米銀結構的多重步驟法[25]	19
表 1-10複雜奈米銀結構的應用[29~40]	20
表 1-11銀墨水製備的實驗步驟及參數或內容[42]	22
表 1-12製造者資料表上的導電墨水特性[43]	26
表 1-13製備樣品的圖案、線寬、尺寸與測試項目對照表[43]	28
表 1-14三種導電墨水材料和多水準固化條件的測試計畫表[43]	30
表 1-15材料清單 (Bill of Material) [44]	32
表 1-16實驗設備清單 (List of Experimental Equipment) [44]	32
表 1-17實驗步驟 (Experimental Steps) [44]	33
表 1-18穿隧電子與滲透原理關係說明表[45]	35
表 1-19滲透理論專有名詞與符號對照表[45]	36
表 1-20滲透現象發生前後專有名詞與符號及數學式對照表[45]	37
表 1-21光子奈米噴流的發展沿革[48~52]	39
表 3-1滲透理論專有名詞與奈米銀棒成長之滲透現象對照表[45]	93
表 3-2光子奈米噴流特徵	96

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