本研究期望發展具快速偵測及攜帶方便的過氧化氫偵測器，並應用於
分析芬頓法處理程序中過氧化氫的濃度。本研究的主要目的是藉由普魯士藍對過氧化氫的獨特催化特性，來有效的降低在電化學上偵測過氧化氫的電位避免干擾。並利用厚膜網版印刷技術來製備印刷電極，以期達到快速、穩定、準確及成本低的量測方式，以厚膜網版印刷技術製備的普魯士藍印刷修飾電極，可用於環境廢水中的過氧化氫偵測，研究中，並藉由實際廢水的量測比較，探討過氧化氫濃度與COD 之間的相互關係。

This research expects to develop a hydrogen peroxide detector which fast detect and carries easily, and applies in analyzing the hydrogen peroxide concentration after Fenton reaction. First, we used the Purssian blue as a catalyzer to decrease the detection potential of hydrogen peroxide to hope to avoid the reference in electrochemistry. The screen printed technology owns many advantages such as fast, stable, accurate and low cost. For electrochemical detector, the Prussian modified electrode was fabricated by screen printed technology. The modified
electrode was application to detect the concentration of hydrogen peroxide in environment wastewater, and demonstrated the relationship between COD and the concentration of hydrogen peroxide.

目錄(Contents)
中文摘要...................................................i
英文摘要...................................................i
目錄(Contents)...........................................iii
圖目錄....................................................vi
表目錄...................................................vii
第一章 緒論................................................1
1-1 前言...................................................1
1-2 染整廢水特性及處理排放.................................1
1-2-1 染整廢水與處理技術...................................1
1-2-2 高級氧化程序的應用...................................5
1-2-3 芬頓法簡介...........................................8
1-3 化學修飾電極簡介......................................12
1-3-1 化學吸附法..........................................12
1-3-2 共價鍵結法..........................................13
1-3-3 高分子薄膜塗佈法....................................14
1-3-4 非均勻相材料混合法..................................15
1-4 混價化合物性質與應用..................................16
1-4-1 混價化合物之性質....................................16
1-4-2 混價化合物修飾電極..................................18
1-4-3 混價化合物在分析上之應用............................22
1-5 厚膜印刷技術在化學感測器上的應用......................25
1-6 過氧化氫感測器之偵測原理..............................26
1-7 本實驗目的............................................28
第二章 實驗部份...........................................29
2-1 儀器與設備............................................29
2-2 藥品..................................................29
2-3 電極的製備............................................30
2-3-1 普魯士藍製備........................................30
2-3-2 印製電極............................................31
2-4 實驗條件設計..........................................31
2-4-1 普魯士藍比例的探討..................................31
2-4-2 操作電位的探討......................................31
2-4-3 緩衝溶液酸鹼值的探討................................32
2-4-4 緩衝溶液種類探討....................................32
2-4-5 緩衝溶液濃度探討....................................32
2-4-6 離子強度探討........................................32
2-4-7 過氧化氫感測器特性探討..............................33
2-4-8 相關性探討..........................................33
2-4-9 模擬樣品量測........................................33
2-5 化學需氧量標準量測....................................33
2-6 過氧化氫標準方法量測..................................34
第三章 實驗結果與討論.....................................36
3-1 普魯士藍感測器特性....................................36
3-2 過氧化氫感測器條件最佳化..............................42
3-2-1 修飾比例最佳化探討..................................42
3-2-2 偵測電位最佳化探討..................................44
3-2-3 環境酸鹼值最佳化探討................................44
3-2-4 緩衝溶液種類探討....................................47
3-2-5 緩衝溶液濃度探討....................................50
3-2-5 離子強度探討........................................50
3-3 過氧化氫感測器之分析特性..............................52
3-3-1 過氧化氫感測器分析特性..............................54
3-3-2 干擾物的探討........................................57
3-3-3 相關性探討..........................................58
3-3-4 模擬樣品量測........................................61
3-3-5 COD 值探討..........................................61
3-3-6 實際樣品量測........................................65
第四章 結論...............................................66
參考文獻..................................................67
圖目錄
圖(一)芬頓法循環反應示意圖................................10
圖(二) 可溶性PB 推測結構..................................18
圖(三）PB 電極在 pH 3, 0.1 M KCl 下之CV 圖................20
圖(四）PB 的結構與其對應之氧化還原示意圖..................21
圖(五)：普魯士藍修飾電極之循環伏安圖......................38
圖(六)：普魯士藍修飾電極對過氧化氫偵測電位................40
圖(七)：普魯士藍感測器之電子傳遞機制示意圖................41
圖(八)：過氧化氫連續添加..................................43
圖(九)：普魯士藍修飾比例之探討............................45
圖(十)：偵測電位探討......................................46
圖(十一)：環境酸鹼值探討..................................48
圖(十二)：緩衝溶液種類探討................................49
圖(十三)：緩衝溶液濃度探討................................51
圖(十四)：離子強度探討....................................53
圖(十五)：校正曲線........................................55
圖(十六)：過氧化氫感測器再現性探討........................56
圖(十七)：相關性探討......................................60
圖(十八)：過氧化氫對COD 值探討............................63
圖(十九)：染料進行芬頓法後COD 值探討......................64
表目錄
表(一) 常見的氧化劑之相對氧化能力..........................6
表(二)：實驗條件最佳化....................................54
表(三)：分析特性..........................................57
表(四)干擾物探討..........................................59
表(五)染整廢水探討........................................61
表(六)COD 值探討..........................................65

1 王嘉儒，染整廢水處理，中國大百科全書環境科學卷，智慧藏百
科全書網
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