系統識別號 | U0002-1308200908290500 |
---|---|
DOI | 10.6846/TKU.2009.00403 |
論文名稱(中文) | 感測重金屬離子的有機分子合成研究 |
論文名稱(英文) | Synthesis of Heavy Metal Cation Sensing Molecules |
第三語言論文名稱 | |
校院名稱 | 淡江大學 |
系所名稱(中文) | 化學學系碩士班 |
系所名稱(英文) | Department of Chemistry |
外國學位學校名稱 | |
外國學位學院名稱 | |
外國學位研究所名稱 | |
學年度 | 97 |
學期 | 2 |
出版年 | 98 |
研究生(中文) | 林振弘 |
研究生(英文) | Jen- Hung Lin |
學號 | 696160208 |
學位類別 | 碩士 |
語言別 | 繁體中文 |
第二語言別 | |
口試日期 | 2009-06-16 |
論文頁數 | 85頁 |
口試委員 |
指導教授
-
李世元(adamlee@mail.tku.edu.tw)
委員 - 林俊成(cclin66@mx.nthu.edu.tw) 委員 - 蔡厚仁(hjtsai@ccit.edu.tw) 委員 - 王伯昌(bcw@mail.tku.edu.tw) |
關鍵字(中) |
鉗合 重金屬 化學感測器 |
關鍵字(英) |
Chelating Heavy metal Chemosensor |
第三語言關鍵字 | |
學科別分類 | |
中文摘要 |
設計以鄰苯二胺為核心架構的化學感測分子,外層接上咔唑來修 飾核心架構上的共軛系統和推拉電子性,另外在二胺官能基的地方做 乙二胺的延伸,使整體具有一個離子結合位置。先藉由UV-Vis測量 其最大吸收波長 ,接著再用不同金屬離子的無機鹽纇來滴定此化合 物透過UV-Vis來觀察吸收波長變化 。 |
英文摘要 |
Synthesis of heavy metal cation sensing molecules based on 0-Phenylenediamine. It possesses conjugate property, and push-pull system. It can be a good Organic Light Emitting Diode. We employ 0-Phenylenediamine’s amino group to synthetize a good binding site. Finally, we titrate with solution which include heavy metal cation following measure the maximum UV- Vis wavelength. We observe color change |
第三語言摘要 | |
論文目次 |
目錄 中文摘要................................................................................................i 英文摘要..............................................................................................ii 第一章 緒論…………………………………………………………..1 1-1 重金屬污染………………………………………………..2 1-2 偵測重金屬陽離子的方法………………………………..8 1-3 化學感測器………………………………………………10 第二章 結果與討論…………………………………………………20 2-1 兩端為推電子官能基的鄰苯二胺分子合成……………20 2-2 發光性質討論……………………………………………44 2-3 金屬離子的滴定…………………………………………46 第三章 實驗與儀器…………………………………………………51 3-1 實驗儀器與測試方法……………………………………51 3-2 溶劑的乾燥………………………………………………54 3-3 反應條件及實驗步驟……………………………………56 第四章 結論…………………………………………………………68 第五章 光譜…………………………………………………………70 第六章 參考資料……………………………………………………82 Scheme目錄 Scheme 1-1………………………………………...…………………10 Scheme 1-2…………………………………………………………...12 Scheme 1-3…………………………………………………………...13 Scheme 1-4…………………………………………………………...14 Scheme 1-5………………………………………………………...…15 Scheme 1-6…………………………………………………………...16 Scheme 1-7…………………………………………………………...16 Scheme 1-8…………………………………………………………...17 Scheme 1-9…………………………………………………………...18 Scheme 1-10………………………………………………………….18 Scheme 1-11……………………………………………………….....19 Scheme 2-1…………………………………………………………...21 Scheme 2-2…………………………………………………………...22 Scheme 2-3…………………………………………………………...22 Scheme 2-4…………………………………………………………...23 Scheme 2-5…………………………………………………………...23 Scheme 2-6…………………………………………………………...24 Scheme 2-7…………………………………………………………...24 Scheme 2-8…………………………………………………………...24 Scheme 2-9…………………………………………………………...25 Scheme 2-10………………………………………………………….26 Scheme 2-11………………………………………………………….27 Scheme 2-12………………………………………………………….27 Scheme 2-13………………………………………………………….28 Scheme 2-14………………………………………………………….29 Scheme 2-15………………………………………………………….30 Scheme 2-16………………………………………………………….31 Scheme 2-17………………………………………………………….32 Scheme 2-18………………………………………………………….33 Scheme 2-19………………………………………………………….33 Scheme 2-20………………………………………………………….34 Scheme 2-21………………………………………………………35-36 Scheme 2-22………………………………………………………….37 Scheme 2-23………………………………………………………….39 Scheme 2-24………………………………………………………….40 Scheme 2-25………………………………………………………….41 Scheme 2-26………………………………………………………….41 Scheme 2-27………………………………………………………….41 Scheme 2-28………………………………………………………….42 Scheme 2-29………………………………………………………….42 Scheme 2-30………………………………………………………….43 Scheme 2-31………………………………………………………….44 Scheme 2-32………………………………………………………….47 Scheme 2-33………………………………………………………….47 Scheme 2-34………………………………………………………….48 Scheme 2-35………………………………………………………….49 Scheme 2-36………………………………………………………….49 Scheme 2-37………………………………………………………….50 Scheme 4-1…………………………………………..……………….68 Scheme 4-2…………………………………………………..……….69 Scheme 4-3…………………………………………………..……….69 光譜目錄 2,1,3-Benzothiadiazole………………………………………………………………70 4,7-Dibromo-2,1,3-benzothiadiazole…………………..…………………………… 71 Tributyl(thiophen-2-yl)stannane……………………………………………………..72 4,7-Dibromo-2,1,3-benzothiadiazole…………………………..…………………….73 4,4,5,5-tetramethyl-2-(thiophen-2-yl)-1,3,2-dioxaborolane………………………….74 5-(4-(thiophen-2-yl)benzo[c][1,2,5]thiadiazol-7-yl)thiophene-2-carbaldehyde...……75 3-((5-(4-(thiophen-2-yl) benzo[c][1,2,5]thiadiazol-7-yl)thiophen-2-yl)mehyleneamino)propan-1-ol……….…76 3-methyl-1-phenyl-4-((5-(4-(thiophen-2-yl) benzo[c][1,2,5]thiadiazol-7-yl)thiophen-2-yl)methylene)-1H-pyrazol-5-one…….. …77 Diethyl -2-((5-(4-(thiophen-2-yl) benzo[c][1,2,5]thiadiazol-7-yl)thiophen-2-yl)methylene)malonate…………………..78 2-((5-(4-(thiophen-2-yl) benzo[c][1,2,5]thiadiazol-7-yl)thiophen-2-yl)methylene)malonic acid………………79 9-(4-(9H-carbazol-9-yl)benzo[c][1,2,5]thiadiazol-7-yl)-9H-carbazole …. ………….80 N,N'- (3,6-di(9H-carbazol-9-yl)-1,2-phenylene)bis(2-acetamidoacetamide)……………….81 |
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