系統識別號 | U0002-0806201201404400 |
---|---|
DOI | 10.6846/TKU.2012.00306 |
論文名稱(中文) | PLA/PTT複合材料之製備及性質測定 |
論文名稱(英文) | Preparation and properties of PLA/PTT composites |
第三語言論文名稱 | |
校院名稱 | 淡江大學 |
系所名稱(中文) | 化學工程與材料工程學系碩士班 |
系所名稱(英文) | Department of Chemical and Materials Engineering |
外國學位學校名稱 | |
外國學位學院名稱 | |
外國學位研究所名稱 | |
學年度 | 100 |
學期 | 2 |
出版年 | 101 |
研究生(中文) | 馬瑞克 |
研究生(英文) | Marek Sipos |
學號 | 698401196 |
學位類別 | 碩士 |
語言別 | 英文 |
第二語言別 | |
口試日期 | 2012-05-10 |
論文頁數 | 94頁 |
口試委員 |
指導教授
-
林國賡
共同指導教授 - 董崇民 共同指導教授 - 賴森茂 委員 - 林國賡 委員 - 董崇民 委員 - 賴森茂 |
關鍵字(中) |
聚乳酸 聚對苯二甲酸丙二醇酯 mPOE cellulose |
關鍵字(英) |
PLA PTT mPOE cellulose Cloisite 30B tensile modulus composite |
第三語言關鍵字 | |
學科別分類 | |
中文摘要 |
本研究從事三成分高分子複材(PLA/PTT/filler)之開發,以及其各種機 械和流變性質之比較。本研究之基材為聚乳酸(PLA)和聚對苯二甲酸丙 二醇酯(PTT)之摻和物。三種不同的填充材分別為馬來酸酐接枝聚(乙 烯 - 辛烯)(mPOE),天然的醋酸纖維素以及納米黏土Cloisite 30B。 首先,藉由DSC和SEM針對含不同成分PPT基材之實驗研究,證實其存 在兩個不同玻璃轉變溫度(Tg)和兩個不相容的相(phase)。 mPOE本質是橡膠,通常作為一種增韌劑,固其添加會增強材料的耐 衝擊強度。另一方面,mPOE亦可以增加PLA的結晶度和提升其楊氏係數, SEM顯示PLA/PTT/mPOE具有三相的微結構。 當基材PLA/PTT添加醋 酸纖維素,其機械性質仍可保持在適度的值,雖然與mPOE趨勢是相反的, 隨著纖維素添加量的增加,其衝擊強度、楊氏係數和基材結晶度都呈下降 趨勢。與其他填充料相比,單位體積納米黏土具有高表面積特性,故只添 加極少量卻有良好的機械性質。但是,Cloisite 30B 的添加量如高達 3%,所有機械性質均會下降,這可能是由於納米顆粒集聚,造成分散不 均的結果。 |
英文摘要 |
Ternary blends with a matrix of poly(lactic acid) (PLA) and poly(trimethylene terephthalate) (PTT) were studied. The third component added was maleic anhydride grafted poly(ethylene octene) (mPOE), because grafted copolymers are often used as compatibilizers in immiscible matrices. Another filler was cellulose acetate, as a natural filler and Cloisite 30B as a nanoclay. Firstly matrix with various amounts of PTT was investigated. DSC and SEM results confirms immiscibility by showing two different glass transition temperatures (Tg) and two distinguishable phases. Mechanical properties of the mixtures are between the values for pure PLA and pure PTT. Addition of mPOE increases Izod impact strength, as it is rubbery component. On the other hand, mPOE increases crystallinity in PLA phase and higher amount of mPOE lowers Young's modulus. SEM pictures show creation of ternary phase. Cellulose acetate keeps mechanical properties in moderate values although the trend is opposite to mPOE. With higher amount of cellulose impact strength was decreased, Young's modulus increased and crystallinity of the matrix was decreased as well. Nanoclay showed best properties with small addition, which is related to highest surface area compared to the same volume of other fillers. With the addition of 3% of 30B, all mechanical properties decreased which can be the result of agglomeration of nanoparticles in microscale causing concentration of tension. |
第三語言摘要 | |
論文目次 |
TABLE OF CONTENTS Index of Tables.........................................................................5 List of figures and illustrations................................................6 1 Introduction......................................................................................1 2 Theoretical background....................................................................3 2.1 Polymer crystalline region.........................................................5 2.2 Polymer mixing...........................................................................8 2.3 Rheology...................................................................................10 2.3.1 Oscillatory testing.............................................................11 2.4 Tensile test...............................................................................16 2.5 Impact test...............................................................................16 2.6 DSC...........................................................................................17 2.7 Previous studies.......................................................................19 2.7.1 Matrix of PLA and PTT......................................................19 2.7.2 PTT as a matrix..................................................................20 2.7.3 PLA as a matrix..................................................................22 2.7.4 Filler addition....................................................................23 3 Experiments....................................................................................25 3.1 Materials..................................................................................25 3.1.1 Polylactic acid....................................................................25 3.1.2 Polytrimethylene terephthalate.........................................25 3.1.3 Maleic anhydride-grafted polyethylene-octene elastomer 26 3.1.4 Cellulose acetate propionate.............................................27 3.1.5 Clay....................................................................................27 3.2 Devices.....................................................................................29 3.3 Experiment procedure.............................................................30 3.3.1 Blends and samples preparation.......................................31 3.3.2 Izod impact test.................................................................34 3.3.3 Tensile test.........................................................................34 3.3.4 Differential scanning calorimetry experiment..................34 3.3.5 Scanning electron microscope observation.......................35 3.3.6 Rheological experiment.....................................................35 4 Results and discussion....................................................................36 4.1 Izod impact test........................................................................36 4.2 Tensile test...............................................................................38 4.3 Differential scanning calorimetry............................................49 4.4 Scanning electron microscope.................................................62 4.5 Rheological experiment............................................................73 4.6 Conclusion................................................................................88 Bibliography...........................................................................90 INDEX OF TABLES Table 3.1: Properties of PTT...............................................................26 Table 3.2: Properties of Cloisite 30B.................................................28 Table 3.3: Two component mixture labeling and the weight of its components........................................................................................32 Table 3.4: Labeling mixtures with mPOE and the weight of its components........................................................................................33 Table 3.5: Labeling mixtures with cellulose acetate and the weight of its components...................................................................................33 Table 3.6: Labeling mixtures with 30B and the weight of its components........................................................................................33 Table 4.1: DSC data of PLA/PTT blends after first heating at the rate of 10°C/min and calculated crystallinity............................................51 Table 4.2: data of PLA/PTT blends after the second heating at the rate of 10°C/min and calculated crystallinity....................................52 Table 4.3: DSC data of PLA/ 20%PTT blends and 1 and 3% of fillers mPOE, cellulose and 30B after first heating at the rate of 10°C/min and calculated crystallinity................................................................53 Table 4.4: DSC data of PLA/ 20%PTT blends and 1 and 3% of fillers mPOE, cellulose and 30B after the second heating at the rate of 10°C/min and calculated crystallinity................................................54 Table 4.5: DSC data of PLA/ 30%PTT blends and 1 and 3% of fillers mPOE, cellulose and 30B after first heating at the rate of 10°C/min and calculated crystallinity................................................................55 Table 4.6: DSC data of PLA/ 30%PTT blends and 1 and 3% of fillers mPOE, cellulose and 30B after the second heating at the rate of 10°C/min and calculated crystallinity................................................56 LIST OF FIGURES AND ILLUSTRATIONS Fig. 1.1: Use of nonwovens, felts and mouldings in the automotive industry................................................................................................2 Fig. 2.1: Examples of crystalline polymers with symmetrical side groups..................................................................................................7 Fig. 2.2: Examples of polymers with nonsymetrical side groups........8 Fig. 2.3: Morphology of immiscible two component blend. From left to right content of polymer B is increasing.2......................................9 Fig. 2.4: Shear stress of a body..........................................................11 Fig. 2.5: Scheme of an oscillatory test...............................................15 Fig. 2.6: A typical graph of viscoelastic modules and their frequency dependency. [17]................................................................................15 Fig. 2.7: Sample for tensile test according to ASTM D638. D is a distance between grips, w is a width of narrow section....................16 Fig. 2.8: Hydrolytic degradation of PLA/PTT mixtures......................20 Fig. 3.1: Structure of Polylactic acid and its monomers: a) L-lactic acid; b) D-lactic acid; c) general structure of PLA.............................25 Fig. 3.2: Chemical structure of PTT...................................................26 Fig. 3.3: Structure of a) polyethylene-octene and b) maleic anhydride ...........................................................................................................27 Fig. 3.4: Chemical structure of cellulose acetate propionate. R = COCH2CH3................................................................................27 Fig. 3.5: Structure of nanoclay Cloisite 30B. T is for tallow, which consists of about 65% C18, 30% C16, 5% C14..................................28 Fig. 3.6: Experiment procedure for three component mixture..........30 Fig. 4.1: Izod impact strength of PLA/PTT blends.............................36 Fig. 4.2: Izod impact strength of PLA / 20%PTT blend with various fillers..................................................................................................37 Fig. 4.3: Izod impact strength of PLA / 30%PTT blend with various fillers..................................................................................................37 Fig. 4.4: Young's modulus of PLA blends with various amount of PTT. Dashed line is a linear fitting curve.3................................................40 Fig. 4.5: Elongation at break for PLA blends with various amount of PTT. Dashed line is a decay fitting curve.4........................................40 Fig. 4.6: Maximum stress for PLA blends with various amount of PTT. Dashed line is a decay fitting curve .5...............................................41 Fig. 4.7: Break stress for PLA blends with various amount of PTT. Dashed line is a decay fitting curve .6...............................................41 Fig. 4.8: Young's modulus of PLA/ 20%PTT with various fillers........42 Fig. 4.9: Elongation at break of PLA/ 20% PTT with various fillers.. 42 Fig. 4.10: Maximum stress of PLA/ 20%PTT blend with various fillers. ...........................................................................................................43 Fig. 4.11: Break stress of PLA/ 20%PTT with various fillers.............43 Fig. 4.12: Young's modulus of PLA/ 30% PTT blend with various fillers..................................................................................................44 Fig. 4.13: Elongation at break of PLA/ 30%PTT with various fillers. 44 Fig. 4.14: Maximum stress of PLA/ 30%PTT blend with various fillers. ...........................................................................................................45 Fig. 4.15: Break stress of PLA/ 30%PTT blend with various fillers.. .45 Fig. 4.16: Plot of tensile test data of PTT and PLA sample................46 Fig. 4.17: Plot of a tensile test data of PLA/PTT blends....................46 Fig. 4.18: Plot of tensile test experiment of the mixtures with mPOE. ...........................................................................................................47 Fig. 4.19: Plot of tensile test experiment of the mixtures with cellulose.............................................................................................47 Fig. 4.20: Plot of tensile test experiment of the mixtures with 30B.. 48 Fig. 4.21: DSC results of PLA blends with 50, 30, 20 and 10% of PTT from the first heating.........................................................................57 Fig. 4.22: DSC results of PLA blends with 50, 30, 20 and 10% of PTT from the second heating....................................................................57 Fig. 4.23: DSC results of PLA/20% PTT mixture after first heating with addition of 1 and 3% of cellulose and 30B.................................58 Fig. 4.24: DSC results of PLA/20% PTT mixture after first heating with addition of 1 and 3% of mPOE...................................................58 Fig. 4.25: DSC results of PLA/20% PTT mixture after second heating with addition of 1 and 3% of cellulose and 30B.................................59 Fig. 4.26: DSC results of PLA/20% PTT mixture after second heating with addition of 1 and 3% of mPOE...................................................59 Fig. 4.27: DSC results of PLA/30% PTT mixture after first heating with addition of 1 and 3% of cellulose and 30B.................................60 Fig. 4.28: DSC results of PLA/30% PTT mixture after first heating with addition of 1 and 3% of mPOE...................................................60 Fig. 4.29: DSC results of PLA/30% PTT mixture after the second heating with addition of 1 and 3% of cellulose and 30B....................61 Fig. 4.30: DSC results of PLA/30% PTT mixture after the second heating with addition of 1 and 3% of mPOE......................................61 Fig. 4.31: SEM images of pure PLA sample at the magnification of 1K, 5K and 10K..................................................................................64 Fig. 4.32: SEM images of pure PTT sample at the magnification of 1K, 5K and 10K..................................................................................64 Fig. 4.33: SEM images of PLA with 50, 30, 20 and 10% PTT at the magnification of 1K............................................................................65 Fig. 4.34: SEM images of PLA with 50, 30, 20 and 10% PTT at the magnification of 5K............................................................................65 Fig. 4.35: SEM images of PLA with 50, 30, 20 and 10% PTT at the magnification of 10K..........................................................................66 Fig. 4.36: SEM images of PLA with 30, 20 and 10% PTT at the magnification of 30K..........................................................................66 Fig. 4.37: SEM pictures of the composite PLA/ 20% PTT / 1% mPOE ...........................................................................................................67 Fig. 4.38: SEM pictures of the composite PLA / 20% PTT / 3% mPOE ...........................................................................................................67 Fig. 4.39: SEM pictures of the composite PLA / 30% PTT / 1% mPOE ...........................................................................................................68 Fig. 4.40: SEM pictures of the composite PLA / 30% PTT / 3% mPOE ...........................................................................................................68 Fig. 4.41: SEM pictures of the composite PLA / 20% PTT / 1% cellulose.............................................................................................69 Fig. 4.42: SEM pictures of the composite PLA / 20% PTT / 3% cellulose.............................................................................................69 Fig. 4.43: SEM pictures of the composite PLA / 30% PTT / 1% cellulose.............................................................................................70 Fig. 4.44: SEM pictures of the composite PLA / 30% PTT / 3% cellulose.............................................................................................70 Fig. 4.45: SEM pictures of the composite PLA / 20% PTT / 1% 30B. 71 Fig. 4.46: SEM pictures of the composite PLA / 20% PTT / 3% 30B. 71 Fig. 4.47: SEM pictures of the composite PLA / 30% PTT / 1% 30B. 72 Fig. 4.48: SEM pictures of the composite PLA / 30% PTT / 3% 30B. 72 Fig. 4.49: Activation energies for PLA/PTT blends............................75 Fig. 4.50: Activation energies for the blend PLA/20%PTT with various fillers..................................................................................................75 Fig. 4.51: Activation energies for the blend PLA/30%PTT with various fillers..................................................................................................76 Fig. 4.52: Complex viscosity of PLA/PTT blends................................76 Fig. 4.53: Storage modulus of PLA/PTT blends.................................77 Fig. 4.54: Loss modulus of PLA/PTT blends.......................................77 Fig. 4.55: Complex viscosity of a blend PLA/20%PTT with 1 and 3% of cellulose and 30B...........................................................................78 Fig. 4.56: Storage modulus of a blend PLA/20%PTT with 1 and 3% of cellulose and 30B...............................................................................78 Fig. 4.57: Loss modulus of a blend PLA/20%PTT with 1 and 3% of cellulose and 30B...............................................................................79 Fig. 4.58: Complex viscosity of a blend PLA/20% PTT with 1 and 3% of mPOE.............................................................................................79 Fig. 4.59: Storage modulus of a blend PLA/20% PTT with 1 and 3% of mPOE.................................................................................................80 Fig. 4.60: Loss modulus of a blend PLA/20% PTT with 1 and 3% of mPOE.................................................................................................80 Fig. 4.61: Complex viscosity of a blend PLA/30%PTT with 1 and 3% of cellulose and 30B...........................................................................81 Fig. 4.62: Storage modulus of a blend PLA/30%PTT with 1 and 3% of cellulose and 30B...............................................................................81 Fig. 4.63: Loss modulus of a blend PLA/30%PTT with 1 and 3% of cellulose and 30B...............................................................................82 Fig. 4.64: Complex viscosity of a blend PLA/30% PTT with 1 and 3% of mPOE.............................................................................................82 Fig. 4.65: Storage modulus of a blend PLA/30% PTT with 1 and 3% of mPOE.................................................................................................83 Fig. 4.66: Loss modulus of a blend PLA/30% PTT with 1 and 3% of mPOE.................................................................................................83 Fig. 4.67: Complex viscosity from temperature sweep of PLA blends with various amount of PTT................................................................84 Fig. 4.68: Plot of complex viscosity vs. 1/temperature. For the mixtures of PLA and PTT two slopes can be observed - one above 230°C and one below 230°C..............................................................84 Fig. 4.69: Storage modulus (G') and loss modulus (G') of PLA/PTT blends with focus in PLA melting area..............................................85 Fig. 4.70: Storage modulus (G') and loss modulus (G') of PLA/PTT blends with focus in PTT melting area..............................................85 Fig. 4.71: Complex viscosity of PLA/20%PTT mixture with 1 and 3% of cellulose and 30B...........................................................................86 Fig. 4.72: Complex viscosity of PLA/20%PTT mixture with 1 and 3% of mPOE.............................................................................................86 Fig. 4.73: Complex viscosity of PLA/30%PTT mixture with 1 and 3% of cellulose and 30B...........................................................................87 Fig. 4.74: Complex viscosity of PLA/30%PTT mixture with 1 and 3% of mPOE.............................................................................................87 |
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