超斥水合成物及其超斥水的應用已被大量研究及使用，但基於許多超斥水合成物含有氟或將超斥水合成物塗佈於各種基材表面時，該超斥水合成物塗層由於被磨擦或沖刷，會失去超斥水的特性，基於超斥水合成物塗層的無毒與可靠度，本研究將含有高壓容器容積比例為70%之二乙烯苯單體、乙酸乙酯溶劑及偶氮二異丁腈起始劑之A混合溶液，進行高壓溶劑熱法已成功製備無毒且具有超斥水之聚二乙烯苯(PDVB)合成物，壓製成PDVB超斥水薄片時，其靜態接觸角與滑動角分別約為163°及1°。將已去木質素的木粉與含有高壓容器容積比例為70%之A混合溶液，經高壓溶劑熱法已成功製備具有超斥水之木粉，將超斥水木粉壓製成片後製成靜態接觸角與滑動角分別約為148°與2°的超斥水木粉薄片。為了增加超斥水合成物塗層的可靠度及其應用，使用環氧樹脂將該超斥水木粉薄片黏接於S25C碳鋼與6061鋁合金形成具有超斥水的複合工件。實驗結果顯示超斥水木粉薄片/環氧樹脂/S25C鐵片複合工件經過耐酸(1M之鹽酸水溶液)鹼(pH13.9之氫氧化鈉)試驗後，該複合工件的靜態接觸角與滑動角約為153°與2°以下。使用6kPa固定負荷的菜瓜布磨擦該複合工件後，該複合工件的靜態接觸角與滑動角約為146°與2°以下。使用含有1wt%細砂(平均粒徑約為300um)之純水沖刷超斥水木粉薄片(內壁)/環氧樹脂/6061鋁管複合工件後，超斥水木粉薄片之靜態接觸角與滑動角略降分別約為140°與18°。另外，將開孔超斥水木粉薄片用螺栓鎖定於兩個中空壓克力管的法蘭後，成功設計一款可有效及快速分離液體中含有氣體之水氣分離模組。

The superhydrophobic material and superhydrophobic application has been widely applied and extensively studied. Some superhydrophobic materials have toxic compounds such as fluoride or these are prone to lose the superhydrophobicity when they are being abraded or eroded. In the present study has successfully made a superhydrophobic coating with non-toxic and long-lasting durability. Firstly, we prepared a non-toxic polydivinylbenzene (PDVB) plates under high pressure solvothermal method with solution A – i.e., mixed solutions of divinylbenzene monomer, ethyl acetate solvent and azobisisobutyronitrile initiator in 70% volume ratio of high pressure vessel. The experimental results showed that the PDVB plate is approximately 163° contact angle and the sliding angle (SA) is about 1°. Additionally, the present experiment using delignined wood powder with similar parameters as above to form a superhydrophbic wood powder plate and produced CA and SA approximately 148° and 2°. In order to improve the durability and application, the superhydrophobic wood powder plate was adhered to S25C carbon steel and 6061 aluminum alloy pipe with epoxy resin to form a superhydrophobic composite workpieces. The experimental results show that the CA and SA is 153° and 2°,respectively during the test of the alkali (pH 13.9 sodium hydroxide)and the acid (1M aqueous solution of HCl) treatment. Additional, the 6kPa fixed load of melon cloth was exerted on the composite workpieces with CA and SA is 146° and 2°. Liquid erosion is using water containing 1wt% fine sand (the average particle size is 300μm) with numbers of CA 140° and SA 18°. In addition, we successfully designed a module that can effectively and quickly separate the gas from the liquid. It is prepared by fixed the openings superhydrophobic wood powder plate between the two flanges of acrylic tube with bolt.

總目錄
壹、導論	1
　1.1前言	1
　1.2文獻回顧	2
　　1.2.1潤濕性質與機制	2
　　　1.2.1.1 Young’s Equation	2
　　　1.2.1.2 Wenzel Model	3
　　　1.2.1.3 Cassie-Baxter Model	3
　　　1.2.1.4滑動角	5
　　1.2.2蓮花效應	6
　　1.2.3木材的結構	9
　　1.2.4木材之去木質素方法	10
　　1.2.5超斥水合成物之製備方法	14
　1.3研究動機	17
貳、實驗步驟	18
　2.1實驗材料	18
　2.2實驗設備	19
　2.3斥水合成物的製備	21
　2.4木粉的去木質素處理	22
　2.5去木質素木粉的斥水處理	23
　2.6斥水合成物/接著劑/S25C鐵片複合工件的製作	24
　2.7 X光繞射儀	28
　2.8傅立葉轉換紅外光譜儀	28
　2.9複合工件A、B、C、D之耐酸鹼試驗	30
　2.10複合工件A、B、C、D之耐刮試驗	30
　2.11複合工件E之沖刷試驗	31
　2.12顯微結構觀察	32
　2.13接觸角量測	32
　2.14滑動角及液滴彈跳量測	33
　2.15水氣分離試驗	33
參、結果與討論	36
　3.1超斥水合成物	36
　　3.1.1 超斥水合成物之聚合反應、型態與晶相分析	36
　　3.1.2 超斥水合成物之FTIR分析	38
　　3.1.3 超斥水薄片之靜態接觸角與滑動角	39
　3.2超斥水木粉	40
　　3.2.1超斥水木粉之外觀型態與顯微結構	40
　　3.2.2超斥水木粉之FTIR分析	44
　　3.2.3水滴在超斥水木粉薄片之靜態接觸角、滑動角與彈跳	46
　3.3超斥水合成物/接著劑/S25C鐵片複合工件之型態與超斥水性
     質	51
　　3.3.1超斥水合成物/接著劑/S25C鐵片複合工件之型態	51
　　3.3.2水滴在超斥水合成物/接著劑/S25C鐵片複合工件之靜態接
    觸角、滑動角與水滴彈跳	55
　　3.3.3超斥水合成物/接著劑/S25C鐵片複合工件的耐酸鹼性質	60
　　3.3.4超斥水合成物/接著劑/S25C鐵片複合工件的耐刮性質	71
　3.4超斥水木粉/環氧樹脂/鋁管複合工件之型態與超斥水性質	77
　3.5水氣分離效果	80
肆、結論	82
伍、參考文獻	84











圖目錄
圖1.1（a）Young’s Equation；（b）Wenzel State；（c）Cassie-Baxter 
　　　State；（d）滑動角之示意圖	4
圖1-2（a）赫蕉；（b）倪藤；（c）玉蘭；（d）歐洲山毛櫸；（e）
　　　蓮；（f）芋；（g）甘藍；（h）Mutisia decurrens之SEM照片	7
圖1-3蓮花表面蠟質結晶（a）低倍率；（b）高倍率之SEM照片	8
圖1-4（a）平滑葉片表面；（b）粗糙葉片表面之自我清潔示意圖	9
圖2-1高壓溶劑熱法（a）設備照片（b）設備內部之示意圖	22
圖2-2（a）斥水合成物/接著劑/S25C鐵片複合工件（b）斥水木粉/
      環氧樹脂/鋁管複合工件之示意圖	27
圖2-3 FTIR示意圖	29
圖2-4耐刮試驗示意圖	30
圖2-5沖刷試驗的示意圖	31
圖2-6開孔斥水合成物薄片上視之示意圖	34
圖2-7（a）斥水薄片固定於壓克力材質法蘭零件中央之示意圖；
（b）水氣分離試驗裝置之照片	35
圖3-1 PDVB之（a）粉末照片；（b）薄片照片；（c）SEM照片；
（d）XRD圖	37
圖3-2 PDVB之FTIR圖	38
圖3-3 PDVB之（a）靜態接觸角照片；（b）滑動角照片	40
圖3-4（a）未作去木質素之木粉；（b）去木質素之木粉；（c）超斥
　　　水木粉粉末；（d）未作去木質素之木粉薄片；（e）去木質素
　　　之木粉薄片；（f）超斥水木粉薄片之照片	42
圖3-5 （a）未作去木質素之木粉；（b）去木質素之木粉；（c）超斥
　　　水木粉粉末；（d）未作去木質素之木粉薄片；（e）去木質素
　　　之木粉薄片；（f）超斥水木粉薄片之SEM照片	43
圖3-6去木質素木粉之FTIR圖	44
圖3-7超斥水木粉之FTIR圖	45
圖3-8（a）未作去木質素之木粉薄片；（b）去木質素之木粉薄片；
（c）超斥水木粉薄片之靜態接觸角照片	48
圖3-9（a）未作去木質素之木粉薄片；（b）去木質素之木粉薄片；
（c）超斥水木粉薄片之滑動角照片	49
圖3-10（a）未作去木質素之木粉薄片；（b）去木質素之木粉薄片；
（c）超斥水木粉薄片之水滴彈跳	50
圖3-11複合工件之示意圖	51
圖3-12（a）拋光後S25C鐵片；（b）超斥水木粉粉末/環氧樹脂/S25C
       薄片；（c）超斥水木粉薄片/環氧樹脂/S25C鐵片；（d）PDVB
       薄片/環氧樹脂/S25C鐵片；（e）超斥水木粉薄片/防鏽漆/S25C
       薄片；（f）防鏽漆/S25C鐵片之照片	53
圖3-13（a）拋光後S25C鐵片；（b）超斥水木粉粉末/環氧樹脂/S25C
       薄片；（c）超斥水木粉薄片/環氧樹脂/S25C鐵片；（d）PDVB
       薄片/環氧 樹脂/S25C鐵片；（e）超斥水木粉薄片/防鏽漆/S25C
       薄片之共軛焦剖斷面照片	54
圖3-14（a）拋光後S25C鐵片；（b）超斥水木粉粉末/環氧樹脂/S25C
       薄片；（c）超斥水木粉薄片/環氧樹脂/S25C鐵片；（d）PDVB
       薄片/環氧樹脂/S25C鐵片；（e）超斥水木粉薄片/防鏽漆/S25C
       薄片之靜態接觸角照片	56
圖3-15（a）拋光後S25C鐵片；（b）超斥水木粉粉末/環氧樹脂/S25C
       薄片；（c）超斥水木粉薄片/環氧樹脂/S25C鐵片；（d）PDVB
       薄片/環氧樹脂/S25C鐵片；（e）超斥水木粉薄片/防鏽漆/S25C
       薄片之滑動角照片	58
圖3-16（a）拋光後S25C鐵片；（b）超斥水木粉粉末/環氧樹脂/S25C
       薄片；（c）超斥水木粉薄片/環氧樹脂/S25C鐵片；（d）PDVB
       薄片/環氧樹脂/S25C鐵片；（e）超斥水木粉薄片/防鏽漆/S25C
       薄片之水滴彈跳	59
圖3-17（a）拋光後S25C鐵片；（b）超斥水木粉粉末/環氧樹脂/S25C
       薄片；（c）超斥水木粉薄片/環氧樹脂/S25C鐵片；（d）PDVB
       薄片/環氧樹脂/S25C鐵片；（e）超斥水木粉薄片/防鏽漆/S25C
       薄片；（f）防鏽漆/S25C鐵片之耐酸試驗後照片	61
圖3-18（a）拋光後S25C鐵片；（b）超斥水木粉粉末/環氧樹脂/S25C
       薄片；（c）超斥水木粉薄片/環氧樹脂/S25C鐵片；（d）PDVB
　　　 薄片/環氧樹脂/S25C鐵片；（e）超斥水木粉薄片/防鏽漆/S25C
       薄片；（f）防鏽漆/S25C鐵片之耐鹼試驗後照片	63
圖3-19（a）拋光後S25C鐵片；（b）超斥水木粉粉末/環氧樹脂/S25C
       薄片；（c）超斥水木粉薄片/環氧樹脂/S25C鐵片；（d）PDVB
       薄片/環氧樹脂/S25C鐵片；（e）超斥水木粉薄片/防鏽漆/S25C
       薄片耐酸後之靜態接觸角照片	66
圖3-20（a）拋光後S25C鐵片；（b）超斥水木粉粉末/環氧樹脂/S25C
       薄片；（c）超斥水木粉薄片/環氧樹脂/S25C鐵片；（d）PDVB
       薄片/環氧樹脂/S25C鐵片；（e）超斥水木粉薄片/防鏽漆/S25C
       薄片耐酸後之滑動角照片	67
圖3-21（a）拋光後S25C鐵片；（b）超斥水木粉粉末/環氧樹脂/S25C
       薄片；（c）超斥水木粉薄片/環氧樹脂/S25C鐵片；（d）PDVB
       薄片/環氧樹脂/S25C鐵片；（e）超斥水木粉薄片/防鏽漆/S25C
       薄片耐鹼後之靜態接觸角照片	69
圖3-22（a）拋光後S25C鐵片；（b）超斥水木粉粉末/環氧樹脂/S25C
       薄片；（c）超斥水木粉薄片/環氧樹脂/S25C鐵片；（d）PDVB
       薄片/環氧樹脂/S25C鐵片；（e）超斥水木粉薄片/防鏽漆/S25C
       薄片耐鹼後之滑動角照片	70
圖3-23（a）拋光後S25C鐵片；（b）超斥水木粉粉末/環氧樹脂/S25C
       薄片；（c）超斥水木粉薄片/環氧樹脂/S25C鐵片；（d）PDVB
       薄片/環氧樹脂/S25C鐵片；（e）超斥水木粉薄片/防鏽漆/S25C
       薄片耐刮試驗前之SEM照片	72
圖3-24（a）拋光後S25C鐵片；（b）超斥水木粉粉末/環氧樹脂/S25C
       薄片；（c）超斥水木粉薄片/環氧樹脂/S25C鐵片；（d）PDVB
       薄片/環氧樹脂/S25C鐵片；（e）超斥水木粉薄片/防鏽漆/S25C
       薄片耐刮試驗後之SEM照片；（f）超斥水木粉薄片/防鏽漆
       /S25C鐵片耐刮試驗後之共軛焦照片	73
圖3-25（a）拋光後S25C鐵片；（b）超斥水木粉粉末/環氧樹脂/S25C
       薄片；（c）超斥水木粉薄片/環氧樹脂/S25C鐵片；（d）PDVB
       薄片/環氧樹脂/S25C鐵片；（e）超斥水木粉薄片/防鏽漆/S25C
       薄片耐刮試驗後之靜態接觸角照片	75
圖3-26（a）拋光後S25C鐵片；（b）超斥水木粉粉末/環氧樹脂/S25C
       薄片；（c）超斥水木粉薄片/環氧樹脂/S25C鐵片；（d）PDVB
       薄片/環氧樹脂/S25C鐵片；（e）超斥水木粉薄片/防鏽漆/S25C
       薄片耐刮試驗後之滑動角照片	76
圖3-27（a）複合工件之照片；（b）複合工件剖斷面之共軛焦照片；
      （c）複合工件沖刷實驗之照片；（d）複合工件沖刷後斷面之
       共軛焦照片；（e）複合工件沖刷後上視圖之SEM照片	78
圖3-28複合工件沖刷後之（a）靜態接觸角照片； （b）滑動角照
       片	79
圖3-29（a）水氣分離主零件；（b）水氣分離試驗；（c）澄清石灰水
       與二氧化碳反應前；（d）澄清石灰水與二氧化碳反應中；
      （e）澄清石灰水與二氧化碳過反應之照片；（f）水氣分離原
       理之示意圖	81

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